Yeah, I have used the pillow stuffing trick with some extreme long distance hunting rounds for Colorado hunting. When shooting up or down some of those mountain sides, you always want the powder up against the primer, no matter what. And, since the pillow stuffing gets consumed during the burn (polyester) , you have to account for that by adjusting the load, working up carefully to your final result. It's certainly an ADVANCED reloading thing, and not for the beginner at all.
Semolina (wheat flour) is the wrong material, and that guy should have his picture on the cover of the Darwin Awards Annual book. He's lucky that people near him didn't also get damaged.
There's a science to fire forming brass. A science. And, anyone thinking of making a wildcat (which is where you need fire formed brass) round, needs to read up on the science first.
I have a book, showing all of the known wildcat cases, what they are made from, how to make them, and suggested loads. If I needed to make a wildcat, I'd still be reviewing any of that with my buddy, Mike Demers in Sanford, Maine (one of the most respected of the New England wildcat experts) before I did anything.