Yes.
So to use those #'s you listed, 6.5 grn's of Unique might produce less felt recoil than 4.8 gr of Titegroup.
A lot of the felt recoil comes from powder design (flake/ sphere/ cylinder) and burn rate/ makeup.
6.5 gr of Unique might produce the around the same felt recoil as 4 grs of Win 231.
Unique is a single base powder, Titegroup would be a double base powder. Titegroup has a faster burn rate.
It can also be a wash if you're just trying to get a certain p.f., then its whatever burns the least amount, burns the cleanest and is super- consistent.
Case pressure "can" be an indicator , but its more of a threshold, like don't exceed X with cartridge A. All that depends on the design of that cartridge. "124 gr 9mm mouse-fart-barely-cycles muh glock "is going to have more case pressure than a 255 .45 acp I'm loading or .45 super, even though the bullet diameter is twice the diameter and twice the weight.
Its voodoo black magic wizardry.